{"id":2715,"date":"2020-07-09T10:18:06","date_gmt":"2020-07-09T10:18:06","guid":{"rendered":"http:\/\/www.alalloycasting.com\/?p=2715"},"modified":"2020-07-15T01:21:17","modified_gmt":"2020-07-15T01:21:17","slug":"liquid-aluminium-purification","status":"publish","type":"post","link":"https:\/\/www.alalloycasting.com\/es\/liquid-aluminium-purification\/","title":{"rendered":"Purificaci\u00f3n del aluminio l\u00edquido"},"content":{"rendered":"

El aluminio l\u00edquido extra\u00eddo de la c\u00e9lula electrol\u00edtica de aluminio contiene numerosas impurezas, lo que no solo afecta al rendimiento de la fundici\u00f3n y el procesamiento del aluminio met\u00e1lico, sino que tambi\u00e9n influye en la calidad del producto. Adem\u00e1s de los elementos met\u00e1licos impuros que acompa\u00f1an a la precipitaci\u00f3n del aluminio durante el proceso de electr\u00f3lisis, existen impurezas s\u00f3lidas no met\u00e1licas (como \u00f3xidos, carburos, nitruros, etc.) y gases disueltos (como H\u2082, CO\u2082, CO, CH\u2084 y N\u2082, entre otros). 100 g de aluminio l\u00edquido disuelven entre 0,2 y 0,4 cm\u00b3 de hidr\u00f3geno a una temperatura de 1273 K. El hidr\u00f3geno presente en el aluminio l\u00edquido se encuentra en dos formas: hidr\u00f3geno at\u00f3mico e hidr\u00f3geno gaseoso. El primero se encuentra disuelto en el aluminio l\u00edquido, mientras que el segundo suele estar adsorbido en las part\u00edculas s\u00f3lidas de inclusiones y debe eliminarse antes de fundir el lingote. Cuando el aluminio l\u00edquido original se funde directamente en diversos lingotes, los requisitos de purificaci\u00f3n del aluminio l\u00edquido son m\u00e1s estrictos, ya que los poros y las inclusiones de escoria en el lingote se convertir\u00e1n directamente en defectos de los productos procesados.<\/p>\n

Purificaci\u00f3n del aluminio l\u00edquido<\/h2>\n

Los m\u00e9todos de purificaci\u00f3n del aluminio l\u00edquido m\u00e1s habituales son el m\u00e9todo de purificaci\u00f3n por filtraci\u00f3n y el m\u00e9todo de purificaci\u00f3n por gas, o una combinaci\u00f3n de ambos en proceso continuo. m\u00e9todo de purificaci\u00f3n<\/a> fuera del horno. Adem\u00e1s, hay quienes utilizan purificaci\u00f3n del fundente<\/a>.<\/p>\n

\"Tecnolog\u00eda<\/p>\n

M\u00e9todo de filtraci\u00f3n y purificaci\u00f3n: m\u00e9todo para purificar las inclusiones no met\u00e1licas presentes en el aluminio l\u00edquido mediante el filtro de espuma cer\u00e1mica<\/a> medio filtrante. El medio filtrante puede consistir en bolas de corind\u00f3n, l\u00e1minas de cer\u00e1mica espumada, tubos cer\u00e1micos microporosos, capas de carb\u00f3n y filtros de seda de silicato fabricados a alta temperatura.<\/p>\n

El m\u00e9todo de purificaci\u00f3n por gas consiste en hacer pasar burbujas de gas inerte o activo a trav\u00e9s del aluminio l\u00edquido para disolver el gas disuelto. Se pueden utilizar gases inertes, como el nitr\u00f3geno y el arg\u00f3n, as\u00ed como gases activos, como el cloro, el tetracloruro de carbono y el hexacloroetano. Cuando se utiliza cloro gaseoso, las burbujas de cloro forman burbujas dispersas de cloruro de aluminio a trav\u00e9s del aluminio l\u00edquido, atrapan las inclusiones s\u00f3lidas en suspensi\u00f3n adsorbidas con hidr\u00f3geno y, a continuaci\u00f3n, flotan hasta la superficie del aluminio l\u00edquido para ser eliminadas. Al mismo tiempo, las impurezas met\u00e1licas como el litio, el potasio, el calcio, el sodio y el magnesio contenidas en el aluminio l\u00edquido pueden eliminarse mediante la cloraci\u00f3n. Sin embargo, el cloro es corrosivo y provoca p\u00e9rdidas de aluminio y contaminaci\u00f3n ambiental, por lo que se utiliza principalmente en combinaci\u00f3n con nitr\u00f3geno. El contenido de cloro suele oscilar entre el 3% y el 6% (fracci\u00f3n volum\u00e9trica). Adem\u00e1s, con el fin de reducir la cantidad de cloruro de aluminio vertida a la atm\u00f3sfera, se puede utilizar el m\u00e9todo de esparcir fundente de cloruro sobre la superficie del aluminio para reducir el contenido de sodio en el aluminio a menos de 0,001%. Este l\u00edquido con bajo contenido en sodio puede utilizarse para la producci\u00f3n de aleaciones de aluminio-magnesio deformables.<\/p>\n

Filtraci\u00f3n y purificaci\u00f3n de gases<\/h2>\n

M\u00e9todo que combina la purificaci\u00f3n continua fuera del horno con la filtraci\u00f3n y la purificaci\u00f3n con gas. El aluminio l\u00edquido se introduce de forma continua en el dispositivo de purificaci\u00f3n, protegido por la capa de recubrimiento de fundente, y se barre con nitr\u00f3geno (o una mezcla de gases). A continuaci\u00f3n, tras pasar por la capa filtrante de bolas de corind\u00f3n, el aluminio l\u00edquido purificado se descarga por la salida. La ventaja de este m\u00e9todo es que permite purificar de forma continua el aluminio l\u00edquido (200-600 kg por minuto), el nitr\u00f3geno no contamina el medio ambiente y ofrece un mejor efecto de purificaci\u00f3n, pudiendo alcanzar una tasa de eliminaci\u00f3n de hidr\u00f3geno de 30%-40%.<\/p>\n

El m\u00e9todo de purificaci\u00f3n con fundente puede utilizarse en una f\u00e1brica o taller de fundici\u00f3n de aluminio a peque\u00f1a escala para el refinado con una mezcla de gases de nitr\u00f3geno y cloro en el horno de fusi\u00f3n, o bien mediante un agente refinador y el refinado con fundente en el horno. Cuando se realiza la colada en el exterior, las inclusiones se eliminan a trav\u00e9s de la malla filtrante, y el resultado tambi\u00e9n es muy bueno. El fundente utilizado suele ser una mezcla de nitrato de sodio y grafito, que aprovecha la descomposici\u00f3n t\u00e9rmica del nitrato de sodio y la reacci\u00f3n con el aluminio para formar \u00f3xidos de nitr\u00f3geno o gas nitr\u00f3geno, con el fin de eliminar las impurezas gaseosas.<\/p>","protected":false},"excerpt":{"rendered":"

The aluminum liquid removed from the aluminum electrolytic cell contains many impurities, which not only affects the casting and processing performance of metal aluminum, but…<\/p>","protected":false},"author":1,"featured_media":2821,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[138],"tags":[823,19,822],"class_list":["post-2715","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-seo","tag-cff-filterer-box","tag-degassing-unit","tag-liquid-aluminium-purification"],"yoast_head":"\nLiquid Aluminium Purification,CFF Filterer Box,Degassing Unit<\/title>\n<meta name=\"description\" content=\"Liquid Aluminium Purification: The method of combining the continuous purification method outside the furnace with filtration and gas purification.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" 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