{"id":6052,"date":"2020-10-25T05:09:46","date_gmt":"2020-10-25T05:09:46","guid":{"rendered":"http:\/\/www.alalloycasting.com\/?p=6052"},"modified":"2020-10-25T05:09:46","modified_gmt":"2020-10-25T05:09:46","slug":"refining-process-for-aluminum","status":"publish","type":"post","link":"https:\/\/www.alalloycasting.com\/pt\/refining-process-for-aluminum\/","title":{"rendered":"Processo de refino de alum\u00ednio"},"content":{"rendered":"

O alum\u00ednio l\u00edquido eletrol\u00edtico apresenta alto teor de g\u00e1s e impurezas. Tendo em vista as caracter\u00edsticas de composi\u00e7\u00e3o acima mencionadas, o processo de refino da massa fundida deve ser refor\u00e7ado. O processo de refino do alum\u00ednio geralmente utiliza agente de refino e inje\u00e7\u00e3o de nitrog\u00eanio; a qualidade do agente de refino e do nitrog\u00eanio deve ser garantida. A produ\u00e7\u00e3o utiliza agente de refino de alta qualidade e nitrog\u00eanio de alta pureza, e realiza dois refinos a uma temperatura de 730-750 \u00b0C. A quantidade de agente de refino utilizada na primeira etapa \u00e9 de 2,5 kg\/t-A, e o tempo de refino \u00e9 de 25 a 30 minutos; ap\u00f3s o refino, a esc\u00f3ria \u00e9 removida, adiciona-se magn\u00e9sio e acende-se o fogo. A dosagem do segundo agente de refino \u00e9 de 1,5 kg\/t, e o tempo de refino \u00e9 de 15 a 20 minutos. Ap\u00f3s a conclus\u00e3o do segundo processo de refino do alum\u00ednio, remove-se a esc\u00f3ria, realiza-se a amostragem e a an\u00e1lise e, ap\u00f3s a composi\u00e7\u00e3o ser aprovada, espalha-se uma camada de agente de cobertura e deixa-se repousar no forno por 30 minutos.<\/p>\n

Processo de refino de alum\u00ednio<\/strong><\/p>\n

Como o ponto de fus\u00e3o do agente de cobertura \u00e9 inferior ao do alum\u00ednio fundido, sua densidade \u00e9 menor do que a do metal fundido, al\u00e9m de possuir boas propriedades de umecta\u00e7\u00e3o. Uma pel\u00edcula protetora l\u00edquida cont\u00ednua \u00e9 formada na superf\u00edcie do metal fundido para isol\u00e1-lo do ar. Em geral, o oxig\u00eanio ou o vapor de \u00e1gua n\u00e3o conseguem, ou raramente conseguem, atravessar a camada de cobertura para reagir com o alum\u00ednio l\u00edquido, e os \u00e1tomos de hidrog\u00eanio dissolvidos no eletr\u00f3lito podem penetrar na camada de cobertura e escapar devido ao seu pequeno raio.<\/p>\n

Adotar refinamento por adsor\u00e7\u00e3o de g\u00e1s<\/a>, o efeito de refino n\u00e3o est\u00e1 apenas intimamente relacionado \u00e0 pureza do nitrog\u00eanio do agente refinador, mas tamb\u00e9m \u00e0 opera\u00e7\u00e3o de refino em si. Isso porque o refino por sopro se baseia na desgaseifica\u00e7\u00e3o por difus\u00e3o de press\u00e3o parcial e na remo\u00e7\u00e3o de esc\u00f3ria por flota\u00e7\u00e3o. Somente a \u00e1rea em contato direto com o g\u00e1s refinado e o p\u00f3 pode apresentar o efeito de refino. Os operadores devem respeitar os procedimentos operacionais e fazer com que o refinador se mova uniformemente ao redor dos quatro cantos do forno de fus\u00e3o, ao longo do fundo do forno, de modo que todo o alum\u00ednio fundido esteja em contato total com o agente de refino e o nitrog\u00eanio, sem deixar cantos mortos.<\/p>\n

\"Processo<\/p>\n

O efeito do refinamento do g\u00e1s depende mais do grau de dispers\u00e3o do g\u00e1s e do tamanho das bolhas. Quanto menor o tamanho das bolhas, melhor \u00e9 o efeito de desgaseifica\u00e7\u00e3o. Isso porque, quanto menores as bolhas, maior \u00e9 o n\u00famero de bolhas geradas pelo mesmo volume de g\u00e1s, maior \u00e9 a \u00e1rea de superf\u00edcie; e quanto mais lenta a velocidade de subida, maior \u00e9 o tempo de contato com a massa fundida. Ao usar um refinador comum em forma de T, o di\u00e2metro das bolhas \u00e9 de cerca de 10 mm, e o efeito \u00e9 muito bom; se for utilizado um tubo de a\u00e7o de 15 mm de di\u00e2metro como refinador, o di\u00e2metro das bolhas pode chegar a mais de 300 mm, e, mesmo com o uso de mais nitrog\u00eanio, o efeito de desgaseifica\u00e7\u00e3o continua sendo insatisfat\u00f3rio.<\/p>\n

Ao adotar o refinamento por adsor\u00e7\u00e3o com fluxo, o agente de refinamento entra em contato direto com o alum\u00ednio fundido, por meio de adsor\u00e7\u00e3o e difus\u00e3o, de modo a alcan\u00e7ar um bom efeito de remo\u00e7\u00e3o de esc\u00f3ria. O efeito de desgaseifica\u00e7\u00e3o do fundente se d\u00e1 principalmente em dois aspectos: um \u00e9 que o fundente se decomp\u00f5e quimicamente e reage com o metal fundido para formar um produto gasoso que permite a difus\u00e3o e a remo\u00e7\u00e3o do hidrog\u00eanio; o outro \u00e9 que a pel\u00edcula de \u00f3xido na superf\u00edcie do metal fundido \u00e9 dissolvida no alum\u00ednio fundido pelo Na\u2083AlF\u2086 presente no fundente, e o hidrog\u00eanio at\u00f4mico se difunde para o g\u00e1s.<\/p>\n

A pr\u00e1tica tem demonstrado que o efeito de remo\u00e7\u00e3o de hidrog\u00eanio e de esc\u00f3ria do m\u00e9todo de refino a g\u00e1s \u00e9 superior ao do m\u00e9todo de refino apenas com fundente. Os dados de medi\u00e7\u00e3o mostram que o teor de hidrog\u00eanio no alum\u00ednio fundido pode ser reduzido para 325 ml\/kg \u00b1 por meio do refinamento no forno, e as inclus\u00f5es de \u00f3xido s\u00e3o significativamente reduzidas; no entanto, isso ainda n\u00e3o atende \u00e0s necessidades da fundi\u00e7\u00e3o do produto, sendo necess\u00e1rio utilizar o sistema de desgaseifica\u00e7\u00e3o em linha e o m\u00e9todo de filtragem CFF para purificar ainda mais o alum\u00ednio fundido. Ap\u00f3s o alum\u00ednio fundido ter sido refinado no forno de repouso est\u00e1tico, o agente de cobertura deve ser espalhado sobre a superf\u00edcie do alum\u00ednio fundido, e o alum\u00ednio fundido deve repousar por 10 a 15 minutos antes de passar para o pr\u00f3ximo processo. O objetivo do repouso \u00e9, por um lado, facilitar que o agente de refino a montante remova o g\u00e1s e as pequenas inclus\u00f5es n\u00e3o met\u00e1licas do alum\u00ednio l\u00edquido para fora da superf\u00edcie do l\u00edquido; por outro lado, facilitar o afundamento das grandes inclus\u00f5es n\u00e3o met\u00e1licas at\u00e9 o fundo do forno.<\/p>","protected":false},"excerpt":{"rendered":"

The electrolytic aluminum liquid has a high content of gas and impurities. In view of the above composition characteristics, the melt refining process must be…<\/p>","protected":false},"author":1,"featured_media":6054,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[233],"tags":[],"class_list":["post-6052","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-blog"],"yoast_head":"\nRefining Process for Aluminum uses refining agent and nitrogen<\/title>\n<meta name=\"description\" content=\"The refining process for aluminum usually uses refining agent and blowing with nitrogen, the quality of the refining agent must be ensured.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.alalloycasting.com\/pt\/refining-process-for-aluminum\/\" \/>\n<meta property=\"og:locale\" content=\"pt_BR\" \/>\n<meta property=\"og:type\" 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