{"id":6992,"date":"2020-12-11T08:59:06","date_gmt":"2020-12-11T08:59:06","guid":{"rendered":"http:\/\/www.alalloycasting.com\/?p=6992"},"modified":"2020-12-11T09:09:04","modified_gmt":"2020-12-11T09:09:04","slug":"flux-for-alkali-metal-removal","status":"publish","type":"post","link":"https:\/\/www.alalloycasting.com\/pt\/flux-for-alkali-metal-removal\/","title":{"rendered":"Fluxo para remo\u00e7\u00e3o de metais alcalinos"},"content":{"rendered":"

Para remover os elementos de metais alcalinos (ou seja, Na, Ca, K, Li), o fluxo para remo\u00e7\u00e3o de metais alcalinos \u00e9 um m\u00e9todo reconhecido para o processamento de alum\u00ednio fundido. Em condi\u00e7\u00f5es de equil\u00edbrio, os cloretos de cada um desses elementos s\u00e3o formados como produtos da rea\u00e7\u00e3o. Com exce\u00e7\u00e3o do LiCl, todos esses sais halogenados s\u00e3o esp\u00e9cies puras e se apresentam na forma s\u00f3lida \u00e0 temperatura normal de processamento; portanto, podem ser facilmente separados na superf\u00edcie da massa fundida como sobrenadante e removidos por escumagem.<\/p>\n

Os elementos dos metais alcalinos geralmente est\u00e3o presentes em concentra\u00e7\u00f5es na massa fundida inferiores a 500 ppm. De acordo com a lei da a\u00e7\u00e3o de massa (a velocidade de rea\u00e7\u00e3o \u00e9 aproximadamente proporcional \u00e0 concentra\u00e7\u00e3o do reagente), formam-se sais metaest\u00e1veis fora do equil\u00edbrio, como o AlCl\u2083 e o MgCl\u2082 (se houver Mg presente). Esses halogenetos s\u00e3o indesej\u00e1veis, pois afetam significativamente a transmiss\u00e3o por ar no processo. Al\u00e9m disso, o MgCl\u2082 funde a 1.306 \u00b0F e geralmente funde em temperaturas normais de processamento de fus\u00e3o. A fus\u00e3o \u00e9 altamente indesej\u00e1vel, pois \u00e9 dif\u00edcil remover o sal que se acumula na superf\u00edcie. Portanto, \u00e9 altamente desej\u00e1vel fazer a rea\u00e7\u00e3o ou complexar os elementos alcalinos para produzir um sal com ponto de fus\u00e3o mais elevado, que seja separado de forma mais eficaz na forma s\u00f3lida por flota\u00e7\u00e3o at\u00e9 a superf\u00edcie.<\/p>\n

Ao dispersar o g\u00e1s de fluxo<\/a> No banho de alum\u00ednio fundido, o fundente para remo\u00e7\u00e3o de metais alcalinos \u00e9 introduzido no corpo principal de forma descendente, ao longo da dire\u00e7\u00e3o axial, e dispersado pelo impulsor girat\u00f3rio instalado no eixo. No entanto, esse m\u00e9todo n\u00e3o \u00e9 ilimitado. O impulsor girat\u00f3rio produz um v\u00f3rtice ao redor do eixo, o que indica que a maior parte do metal fundido gira ou circula ao redor do eixo do impulsor a uma velocidade pr\u00f3xima \u00e0 do pr\u00f3prio impulsor. O metal fundido adicionado ao meio de cultura tende a circular e a fundir metais com dispersibilidade m\u00ednima. Al\u00e9m disso, o v\u00f3rtice tem o efeito de aumentar a \u00e1rea de superf\u00edcie do metal fundido exposta ao ar.<\/p>\n

A maior exposi\u00e7\u00e3o do metal fundido ao ar leva ao aumento da forma\u00e7\u00e3o de esc\u00f3ria, ao seu subsequente arrastamento e aos seus efeitos colaterais prejudiciais. Quando o fundente \u00e9 um g\u00e1s, o v\u00f3rtice pode causar problemas de outra forma. O g\u00e1s fundente \u00e9 separado por for\u00e7a f\u00edsica em dire\u00e7\u00e3o ao centro do v\u00f3rtice, fazendo com que as demais partes sejam deslocadas e o metal fundido n\u00e3o processe adequadamente o g\u00e1s de fus\u00e3o. Portanto, a efic\u00e1cia do m\u00e9todo \u00e9 reduzida devido \u00e0 fus\u00e3o parcial. N\u00e3o utilize o fluxo para tratar o corpo. Al\u00e9m disso, o g\u00e1s de fluxo arrastado no fluxo do metal fundido tende a se aglomerar, resultando na forma\u00e7\u00e3o de bolhas maiores de g\u00e1s de fluxo no metal fundido. Bolhas maiores reduzir\u00e3o a efici\u00eancia do fluxo, pois menos metal fundido \u00e9 processado.<\/p>\n

\"Fluxo<\/p>\n

Entre os m\u00e9todos comuns para suprimir a forma\u00e7\u00e3o de v\u00f3rtices est\u00e3o a inser\u00e7\u00e3o de defletores ou hastes na massa fundida. No entanto, o uso do defletor \u00e9 indesej\u00e1vel devido ao volume morto atr\u00e1s de sua borda traseira. Outro m\u00e9todo para suprimir a forma\u00e7\u00e3o de v\u00f3rtices consiste em limitar a pot\u00eancia fornecida ao impulsor. No entanto, isso reduz drasticamente a efici\u00eancia.<\/p>\n

Portanto, h\u00e1 uma necessidade urgente de um processo de fluxo mais eficaz, capaz de suprimir a reabsor\u00e7\u00e3o da esc\u00f3ria da superf\u00edcie de volta para a massa fundida por meio da forma\u00e7\u00e3o de v\u00f3rtices; por exemplo, fazer com que o material de fluxo fique finamente disperso em toda a massa fundida e aumentar o contato do metal fundido com o fluxo para a remo\u00e7\u00e3o de metais alcalinos, o que pode melhorar o fluxo da massa fundida.<\/p>","protected":false},"excerpt":{"rendered":"

In order to remove alkali metal elements (ie, Na, Ca, K, Li), the flux for alkali metal removal is a recognized method for processing molten…<\/p>","protected":false},"author":1,"featured_media":6994,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[138],"tags":[4335,4333,122,1708,4290,4289,4331,4336,4342,4344,4337,4343,4338,4332,2218,4334,4341,4339,4340,123,4330,4328,4329],"class_list":["post-6992","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-seo","tag-aluminium-casting-flux","tag-aluminium-degassing-tablets","tag-aluminum-casting-flux","tag-aluminum-casting-foundry-flux","tag-aluminum-degassing-flux","tag-aluminum-degassing-tablets","tag-aluminum-flux","tag-aluminum-flux-powder","tag-casting-flux","tag-coverall-flux","tag-degas-tablets","tag-degassing-agent","tag-degassing-tablets","tag-flux-aluminium","tag-flux-for-aluminum-melting","tag-flux-for-melting-aluminum-cans","tag-flux-melting","tag-foundry-flux","tag-low-temperature-flux","tag-refining-flux","tag-tundish-covering-compound","tag-tundish-covering-powder","tag-tundish-powder"],"yoast_head":"\nFlux 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