{"id":6427,"date":"2020-11-14T08:16:12","date_gmt":"2020-11-14T08:16:12","guid":{"rendered":"http:\/\/www.alalloycasting.com\/?p=6427"},"modified":"2020-11-13T09:33:33","modified_gmt":"2020-11-13T09:33:33","slug":"alkali-metals-in-aluminum-melt","status":"publish","type":"post","link":"https:\/\/www.alalloycasting.com\/tr\/alkali-metals-in-aluminum-melt\/","title":{"rendered":"Al\u00fcminyum Eriyi\u011findeki Alkali Metaller"},"content":{"rendered":"<p>Al\u00fcminyum eriyigindeki alkali metaller ve alkali toprak metaller, esas olarak al\u00fcminyum elektroliz s\u00fcrecindeki Na, Li, Ca vb. alkali metaller ve alkali toprak metal elementlerinden ve ayr\u0131ca al\u00fcminyum ala\u015f\u0131m\u0131 ak\u0131\u015fkanlar\u0131ndan kaynaklan\u0131r. <a href=\"http:\/\/www.alalloycasting.com\/tr\/aluminum-alloy-fluxes\/\">Al\u00fcminyum ala\u015f\u0131ml\u0131 eriticiler<\/a> genellikle alkali metaller ve alkali toprak metallerinden olu\u015fur. Klor\u00fcr ve flor\u00fcr\u00fcn ana bile\u015fenleri KCl, NaCl, NaF, CaF, Na\u2083AlF\u2086, Na\u2082SiF\u2086 vb.'dir. Al\u00fcminyum ar\u0131tma ak\u0131\u015fkan\u0131n\u0131n kullan\u0131lmas\u0131ndan sonra, yukar\u0131da belirtilen alkali metaller ve alkali toprak metaller eriyik i\u00e7inde kal\u0131r.<\/p>\n<p>\u00d6rnek olarak alkali metal sodyumu ele alal\u0131m. Sodyum, al\u00fcminyumda neredeyse \u00e7\u00f6z\u00fcnmez ve maksimum kat\u0131 \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc 0,0025%\u201cden azd\u0131r. Al-Mg ala\u015f\u0131m\u0131nda, magnezyum i\u00e7eri\u011fi 2%\u201dyi a\u015ft\u0131\u011f\u0131nda, magnezyum silikonu uzakla\u015ft\u0131r\u0131r ve serbest sodyumu ay\u0131r\u0131r. Na, kat\u0131la\u015fma s\u00fcreci s\u0131ras\u0131nda kat\u0131la\u015f\u0131r. Tah\u0131l s\u0131n\u0131rlar\u0131nda bulunan sodyum, plastik deformasyon s\u00fcrecinde d\u00fc\u015f\u00fck erime noktas\u0131 nedeniyle serbest halini geri kazan\u0131r ve \u00e7atlaklar\u0131n kayna\u011f\u0131n\u0131 olu\u015fturur. Deformasyon miktar\u0131 artt\u0131k\u00e7a, \u00e7atlaklar birle\u015ferek \u00e7atlaklar olu\u015fturur; bu, \"sodyum k\u0131r\u0131lganl\u0131\u011f\u0131\" olarak adland\u0131r\u0131lan fenomendir.<\/p>\n<p>Al\u00fcminyum ala\u015f\u0131m\u0131ndaki kalsiyum, al\u00fcminyumla birlikte CaAl\u2084 ve CaAl\u2082 adl\u0131 yeni fazlar olu\u015fturur. Bu yeni fazlar\u0131n olu\u015fumu, al\u00fcminyum ala\u015f\u0131m\u0131ndaki g\u00fc\u00e7lendirici fazlar\u0131n azalmas\u0131na yol a\u00e7ar. \u00d6rne\u011fin, al\u00fcminyum ala\u015f\u0131m\u0131nda CaAl4 faz\u0131 mevcut oldu\u011funda, mukavemet a\u015famas\u0131 olan \u03b8 faz\u0131 (CuAl2) azal\u0131r ve \u00e7\u00f6zelti ya\u015fland\u0131rma i\u015fleminden sonra al\u00fcminyum ala\u015f\u0131m\u0131n\u0131n sertli\u011fi de azal\u0131r. Mikroyap\u0131 a\u00e7\u0131s\u0131ndan bak\u0131ld\u0131\u011f\u0131nda, CaAl4 faz\u0131 g\u00f6vde merkezli tetragonal bir yap\u0131d\u0131r. Kafes sabitlerinin ve Cu atom yar\u0131\u00e7aplar\u0131n\u0131n birbirine yak\u0131n olmas\u0131 nedeniyle, \u03b8 faz\u0131ndaki Cu, CaAl\u2084'teki Al'\u0131n yerini alarak yeni bir bile\u015fik faz olu\u015fturabilir ve b\u00f6ylece faz azalmas\u0131n\u0131 g\u00fc\u00e7lendirir. Ca i\u00e7eri\u011fi 1,2%'ye ula\u015ft\u0131\u011f\u0131nda, Cu atomlar\u0131 CaAl\u2082'deki iki al\u00fcminyum atomunun yerini alarak yeni bir bile\u015fik faz olu\u015fturur. Bu yeni bile\u015fik, al\u00fcminyum matrisine \u00e7\u00f6z\u00fcnmez ve \u00e7\u00f6kelme ile g\u00fc\u00e7lendirme s\u00fcrecine giremez. Al\u00fcminyum ala\u015f\u0131m\u0131ndaki kalsiyum, d\u00f6k\u00fcm halindeki sertli\u011fi azalt\u0131r; kalsiyum i\u00e7eri\u011fi artt\u0131\u011f\u0131nda, \u0131s\u0131l i\u015flemden sonra al\u00fcminyum ala\u015f\u0131m\u0131n\u0131n sertli\u011fi de azal\u0131r. Ayr\u0131ca, al\u00fcminyum eriyikindeki zararl\u0131 safs\u0131zl\u0131k elementi Ca miktar\u0131 fazla oldu\u011funda, al\u00fcminyum ala\u015f\u0131m\u0131 eriyi\u011finin ak\u0131\u015fkanl\u0131\u011f\u0131 bozulur ve hava ve mikroskobik delikler veya gev\u015feklik olu\u015fmas\u0131 kolayla\u015f\u0131r. Ciddi durumlarda, ayr\u0131\u015fmaya u\u011frayan sert ve k\u0131r\u0131lgan bile\u015fikler olu\u015fur; bu da d\u00f6k\u00fcmlerin hurda oran\u0131n\u0131 \u00f6nemli \u00f6l\u00e7\u00fcde art\u0131r\u0131r ve al\u00fcminyum ala\u015f\u0131mlar\u0131n\u0131n \u0131s\u0131l i\u015flemle g\u00fc\u00e7lendirme etkisini azalt\u0131r.<\/p>\n<p>Mevcut raporlara g\u00f6re, al\u00fcminyum eriyikindeki alkali metalleri gidermek i\u00e7in kullan\u0131labilecek y\u00f6ntem, bir bekletme f\u0131r\u0131n\u0131nda uygulamakt\u0131r<br \/>\nEriyi\u011fin ar\u0131t\u0131lmas\u0131 i\u00e7in klor, klor i\u00e7eren ar\u0131tma maddeleri (heksakloroetan, karbon tetraklor\u00fcr vb.) veya flor\u00fcr i\u00e7eren ar\u0131tma maddeleri kullan\u0131l\u0131r. Ancak, klor, klor\u00fcr veya flor\u00fcr kullan\u0131ld\u0131\u011f\u0131 s\u00fcre\u00e7te, al\u00fcminyum eriyikinden klor gaz\u0131 y\u00fckselir; alkali metallerle reaksiyon sonucu klor gaz\u0131 ve hidrojen flor\u00fcr olu\u015fur; \u0131s\u0131tma sonucu gazla\u015fan heksakloretan ve tetraklor\u00fcr ile karbon gaz\u0131 olu\u015fumu, f\u0131r\u0131n astar\u0131na ciddi zarar verir ve f\u0131r\u0131n\u0131n \u00f6mr\u00fcn\u00fc k\u0131salt\u0131r. \u0130kinci olarak, bu durum \u00fcretim operat\u00f6rleri i\u00e7in mesleki tehlikelere yol a\u00e7ar.<\/p>\n<p>Alkali metaller ve alkali toprak metallerin \u00e7evre dostu ve verimli bir \u015fekilde ayr\u0131\u015ft\u0131r\u0131lmas\u0131, ikame reaksiyonu yoluyla ger\u00e7ekle\u015ftirilir. Temel ilke, metal aktivite s\u0131ras\u0131na g\u00f6re alkali metaller ve alkali toprak metallerin kimyasal \u00f6zelliklerindeki aktif dalga \u00f6zelliklerinden yararlanmak ve nispeten inaktif katyonlara sahip di\u011fer metal tuzlar\u0131n\u0131 eklemektir. Ard\u0131ndan, bu tuzlar di\u011fer fiziksel y\u00f6ntemlerle uzakla\u015ft\u0131r\u0131l\u0131r. Magnezyum i\u00e7eren ala\u015f\u0131mlardan Na'n\u0131n uzakla\u015ft\u0131r\u0131lmas\u0131n\u0131 \u00f6rnek olarak al\u0131rsak, bu i\u015flem genellikle MgCl\u2082 ile elementel Na aras\u0131ndaki ikame reaksiyonu yoluyla ger\u00e7ekle\u015ftirilir. Temel reaksiyon form\u00fcl\u00fc \u015f\u00f6yledir:<br \/>\nMgCl\u2082 + 2Na = 2NaCl + Mg<\/p>\n<p>G\u00fcn\u00fcm\u00fczde, y\u00fcksek performansl\u0131 ala\u015f\u0131mlar b\u00fcy\u00fck boyutlara do\u011fru geli\u015fmekte olup, d\u00f6k\u00fcm levhalara y\u00f6nelik boyut gereksinimleri giderek artmaktad\u0131r. Al\u00fcminyum ala\u015f\u0131m\u0131 eriyikindeki art\u0131k gaz, safs\u0131zl\u0131klar, c\u00fcruf ve alkali\/alkali toprak metaller, d\u00f6k\u00fcm levhan\u0131n i\u015flenmesi ve \u015fekillendirilmesi s\u0131ras\u0131nda daha zararl\u0131 olacakt\u0131r.<\/p>","protected":false},"excerpt":{"rendered":"<p>Alkali metals and alkaline earth metals in aluminum melt mainly come from alkali metals and alkaline earth metal elements in the aluminum electrolysis process, such&hellip;<\/p>","protected":false},"author":1,"featured_media":6492,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[233],"tags":[],"class_list":["post-6427","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-blog"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.9 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Alkali Metals in Aluminum Melt | 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